Verkhovna Rada
In April 1996, he became the People's Deputy of the 2nd convocation of the Verkhovna Rada of Ukraine in Leningradsky electoral district No. 8 in Kyiv. At the time, he was a member of the committee on the basic industries and social-economic development of the regions.
In March 1998, he was elected to the 3rd convocation of the Verkhovna Rada in electoral district No. 212 in Kyiv. That time, he was a member of the Committee on Industrial Policy.
In April 2002, he was reelected to 4th Verkhovna Rada in electoral district No. 219 in Kyiv, elected from the Yushchenko bloc "Our Ukraine". He was a member of the State Committee on national construction and local self-government issues in June 2002, and was the chairman of the subcommittee on election laws and citizens associations. At the 2006 national parliamentary elections his Reforms and Order Party won in an alliance with PORA 1.47 percent of the popular vote and no seats. After the Kyiv local election 2006 Volodymyr Bondarenko became a deputy in the Kyiv City Council for the Vitaliy Klychko Bloc and was in rigid opposition to the team of then mayor Leonid Chernovetsky. He took an active part in political battles that were unfolding almost at every session of the Kyiv City Council. He actively supported the idea of holding a referendum for impeachment of the mayor and City Council team.
In November 2007, he was reelected to the 6th Verkhovna Rada from the Yulia Tymoshenko Bloc, No. 100 in the list, and was a member of the Budget Committee in December, and was chairman of the subcommittee on tracking the influence of legislation on the budget performance in January 2008.
He had been the chairman of the Subcommittee on tracking the impact of legislation on the budget performance, Budget committee of Verkhovna Rada.
He was the Deputy member of the permanent delegation to the Parliamentary Assembly of the Organization for Security and Cooperation in Europe. He was the Member of the Group for Interparliamentary Relations with China, Chile, Japan, Canada, South Africa, Afghanistan, and Italy,
In the 2012 Ukrainian parliamentary election Bondarenko was Batkivshchyna's candidate in single-member districts number 219 (first-past-the-post wins a parliament seat) located in Kyiv; with 44.2 percent of the votes he was reelected into parliament. His Reforms and Order Party merged into All-Ukrainian Union "Fatherland" in June 2013.
In the 2014 parliamentary election Bondarenko was a candidate in single-member districts number 219 in Kyiv, but this time was defeated by Petro Poroshenko Bloc candidate Oleksandr Tretiakov.