History
Until 1796, the guberniya was administered as a Viceroyalty (namestnichestvo). It was initially centred in Zaslav and was called the Zaslav Viceroyalty. It was primarily created from the Kyiv Voivodeship and in 1795 Volhynian Voivodeship whit boder lands of Ruthenian Voivodeship.
On 24 October 1795, the Third Partition of Poland was imposed by Prussia, the Habsburg monarchy, and the Russian Empire.
Then, on 12 December 1796, Volhynia Governorate was established, encompassing the remaining territory of the Wolyn Voivodeship and the Kyiv Voivodeship.
In 1796, the administration moved to Novograd-Volynsky. However, due to the lack of suitable buildings for administrative purposes, the capital was moved once again to Zhitomir (Zhytomyr).
In 1802, Zhitomir was purchased the properties of Prince Ilyinsky, and in 1804, it officially became the seat of Volhynia Governorate.
From 1832 to 1915, Volhynia Governorate, along with Kiev Governorate and Podolia Governorate, formed part of the Southwestern Krai General-Governorate–a militarized administrative-territorial unit.
In the 1880s, the general-governorate was extended to include other governorates.
In 1897, the population of the guberniya was 2,989,482 and by 1905, it had grown to 3,920,400. The majority of the population in the governorate spoke the Ukrainian language with slight variety of dialects.
Under the Russian Provisional Government administrative power in the governorates was transferred to commissars, who preserved their positions after the proclamation of Ukrainian People's Republic in November 1917. Their power was mostly nominal due to the growth of Bolshevik Soviet influence, especially in industrial areas. During that time Andrii Vyazlov served as the gubernial commissar of Volhynia.
During the Ukrainian–Soviet War Zhitomir served as the provisional capital of Ukraine in 1918.
After the return of Central Rada in March 1918 new commissars were appointed along with military commandants. After the establishment of the Hetmanate, in May 1918 those were replaced with Governorate starosts.
After the Polish-Soviet war in 1920, and according to the Peace of Riga (1921) most of the territory became part of the Second Polish Republic and transformed into the Wołyń Voivodeship, with the capital in Łuck (Lutsk). The eastern portion existed until 1925 and was later split into three okruhas: Shepetivka Okruha, Zhytomyr Okruha, and Korosten Okruha.